Index

Oxa-Vinylcyclopropane-Rearrangement

References: 0


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon

Reactants

pH: neutral | no catalyst any solvent high temperature

Products

Ketene-Cycloaddition-3+2

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A

Reactants

pH: acid | no catalyst no_water solvent room temperature

Products

Buchner-Ring-Expansion-C

References: 0


Special Conditions : SIDE REACTION

Reactants

no pH | no catalyst any solvent high temperature

Products

Ketene-Nu-Carboxyl-H

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R3 = H, A-Aromatic-Carbon, A-Aliphatic-Carbon, Vinyl-Group

Reactants

pH: acid | no catalyst no_water solvent room temperature

Products

Oxy-Cope-Rearrangement

References: 0


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A

Reactants

pH: basic | no catalyst any solvent high temperature

Products

Ozonolysis-Alkene-Oxidative

References: 0,1,2,3

Condition to enforce:

R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
R4 = H, A-Aliphatic-Carbon

Reactants

pH: neutral | no catalyst no_water solvent room temperature

Products

Ozonolysis-Alkyne

References: 0,1,2,3,4,5

Condition to enforce:

R1 = A-Aliphatic-Carbon, A-Aromatic-Carbon, H
R2 = A-Aliphatic-Carbon, A-Aromatic-Carbon, H

Reactants

pH: neutral | no catalyst water solvent room temperature

Products

Claisen-Rearrangement

References: 0,1


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A

Reactants

no pH | no catalyst no_water solvent high temperature

Products

1,3-Dipolar-Cycloaddition-Type-I

References: 0

Reactants

pH: neutral | no catalyst any solvent any temperature

Products

Hexadehydro-Diels-Alder-Reaction-Nu-Nitrite-and-El-Hydrogen

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent any temperature

Products

Diels-Alder-4+2-Nitrogen

References: 0,1

Condition to enforce:

R1 = H, A-Aliphatic-Carbon
R2 = L-A
R3 = L-A
R4 = H, A-Aliphatic-Carbon
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A

Avoid formation of:

fragment = 4-membered-ring

Reactants

pH: neutral | no catalyst no_water solvent any temperature

Products

Petasis-Ferrier-Rearrangement

References: 0


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R6 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R7 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R8 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: acid | no catalyst any solvent any temperature

Products

McCormack-Reaction

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R6 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R7 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R8 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R9 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: neutral | no catalyst any solvent any temperature

Products

Neber-Rearrangement

References: 0

Condition to enforce:

R1 = L-A
R2 = L-A, Vinyl-Group
R3 = L-A, Vinyl-Group
R4 = L-A

Reactants

pH: acid | no catalyst water solvent room temperature

Products

Ene-Reaction-C=C

References: 0,1

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A

Avoid formation of:

fragment = 3-membered-ring, 4-membered-ring, 5-membered-ring, A-Cyclobutene, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5

Reactants

pH: neutral | no catalyst no_water solvent high temperature

Products

Claisen-Rearrangement-Aromatic

References: 0,1


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A

Reactants

no pH | no catalyst no_water solvent high temperature

Products

Hexadehydro-Diels-Alder-Reaction-Nu-Carbonyl-and-El-Hydrogen

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent any temperature

Products

Hexadehydro-Diels-Alder-Reaction-Nu-Thiolate-and-El-Hydrogen

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent any temperature

Products

Electrocyclic-Ring-Opening

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
R4 = H, A-Aliphatic-Carbon
R5 = H, A-Aliphatic-Carbon
R6 = H, A-Aliphatic-Carbon

Reactants

no pH | no catalyst any solvent any temperature

Products

Sommelet-Hauser-Rearrangement

References: 0


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent any temperature

Products

Vinylcyclopropane-Rearrangement

References: 0


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon

Reactants

pH: neutral | no catalyst any solvent high temperature

Products

Ketene-Cycloaddition-4+2

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A

Reactants

pH: acid | no catalyst no_water solvent room temperature

Products

Wharton-Reaction

References: 0

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon

Reactants

pH: acid | no catalyst no_water solvent any temperature

Products

Overman-Rearrangement-Pt1

References: 0,1

Condition to enforce:

R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon

Reactants

pH: basic | no catalyst no_water solvent any temperature

Products

Irreversable-Azo-Cope-Rearrangement

References: 0


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A

Reactants

no pH | no catalyst any solvent high temperature

Products

Nazarov-Cyclization

References: 0

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon
R5 = L-A, A-Aromatic-Carbon

Reactants

pH: acid | no catalyst no_water solvent high temperature

Products

Ketene-Nu-Hydroxyl

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group

Reactants

pH: acid | no catalyst no_water solvent room temperature

Products

Diels-Alder-4+2

References: 0,1

Condition to enforce:

R1 = H, A-Aliphatic-Carbon
R2 = L-A
R3 = L-A
R4 = H, A-Aliphatic-Carbon
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A
R10 = L-A

Avoid formation of:

fragment = 4-membered-ring

Reactants

pH: neutral | no catalyst no_water solvent any temperature

Products

Favorskii-Rearrangement-Cl

References: 0,1

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent high temperature

Products

Buchner-Ring-Expansion-N

References: 0


Special Conditions : SIDE REACTION

Reactants

no pH | no catalyst any solvent high temperature

Products

Hexadehydro-Diels-Alder-Reaction-Nu-Hydroxyl-and-El-Hydrogen

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent any temperature

Products

Ene-Reaction-C=O

References: 0,1

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A

Avoid formation of:

fragment = 3-membered-ring, 4-membered-ring, A-Cyclobutene, 5-membered-ring, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5

Reactants

pH: neutral | no catalyst no_water solvent high temperature

Products

Nitrone-Olefin-3+2-Cycloaddition

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

no pH | no catalyst no_water solvent high temperature

Products

Ene-Reaction-C=N

References: 0,1

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A

Avoid formation of:

fragment = 3-membered-ring, 4-membered-ring, A-Cyclobutene, 5-membered-ring, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5

Reactants

pH: neutral | no catalyst no_water solvent high temperature

Products

Aza-Vinylcyclopropane-Rearrangement

References: 0


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon

Reactants

pH: neutral | no catalyst any solvent high temperature

Products

Conia-Ene-Reaction

References: 0

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A

Avoid formation of:

fragment = 3-membered-ring, 4-membered-ring, 5-membered-ring, A-Cyclobutene, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5

Reactants

pH: neutral | no catalyst no_water solvent high temperature

Products

1,3-Dipolar-Cycloaddition-Type-II

References: 0

Reactants

pH: neutral | no catalyst any solvent any temperature

Products

Hexadehydro-Diels-Alder-Reaction-Nu-Amino-and-El-Hydrogen

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
R6 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen

Reactants

pH: basic | no catalyst water solvent any temperature

Products

Ene-Reaction-C=S

References: 0,1

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A

Avoid formation of:

fragment = 3-membered-ring, 4-membered-ring, 5-membered-ring, A-Cyclobutene, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5

Reactants

pH: neutral | no catalyst no_water solvent high temperature

Products

Newman-Kwart-Rearrangement

References: 0


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst no_water solvent high temperature

Products

Staudinger-Synthesis

References: 0

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon

Reactants

pH: acid | no catalyst no_water solvent any temperature

Products

Ozonolysis-Alkyne-Terminal

References: 0,1,2,3,4

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: neutral | no catalyst water solvent room temperature

Products

Buchner-Ring-Expansion-O

References: 0


Special Conditions : SIDE REACTION

Reactants

no pH | no catalyst any solvent high temperature

Products

Aziridine-1-3-Dipole-Formation

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = A-Carbonyl, Nitronium
R3 = A-Carbonyl, Nitronium
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: neutral | no catalyst no_water solvent high temperature

Products

Tiffeneau-Demjanov-Rearrangement

References: 0

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon

Reactants

pH: acid | no catalyst no_water solvent room temperature

Products

Thio-Claisen-Rearrangement

References: 0,1


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A

Reactants

no pH | no catalyst no_water solvent high temperature

Products

Ketene-Nu-Amino

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen

Reactants

pH: acid | no catalyst no_water solvent room temperature

Products

Azo-Vinylcyclopropane-Rearrangement

References: 0


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon

Reactants

pH: neutral | no catalyst any solvent high temperature

Products

Hexadehydro-Diels-Alder-Reaction-Nu-Phosphonate-and-El-Hydrogen

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R6 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent any temperature

Products

Ene-Reaction-N=N

References: 0,1

Condition to enforce:

R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
R4 = H, A-Aliphatic-Carbon
R5 = H, A-Aliphatic-Carbon
R6 = H, A-Aliphatic-Carbon
R7 = H, A-Aliphatic-Carbon

Avoid formation of:

fragment = 3-membered-ring, 4-membered-ring, 5-membered-ring, A-Cyclobutene, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5

Reactants

pH: neutral | no catalyst no_water solvent high temperature

Products

Hexadehydro-Diels-Alder-Reaction-Nu-Carboxyl-and-El-Hydrogen

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent any temperature

Products

Azo-Cope

References: 0


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A

Reactants

pH: basic | no catalyst any solvent high temperature

Products

Diels-Alder-4+2-Oxygen

References: 0,1

Condition to enforce:

R1 = H, A-Aliphatic-Carbon
R2 = L-A
R3 = L-A
R4 = H, A-Aliphatic-Carbon
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A

Avoid formation of:

fragment = 4-membered-ring

Reactants

pH: neutral | no catalyst no_water solvent any temperature

Products

Ketene-Cycloaddition-2+2

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A

Reactants

pH: acid | no catalyst no_water solvent room temperature

Products

Enolate-Claisen-Rearrangement

References: 0,1,2


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A

Reactants

pH: basic | no catalyst any solvent high temperature

Products

Overman-Rearrangement-Pt2

References: 0,1


Special Conditions : SIDE REACTION

Condition to enforce:

R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon

Reactants

pH: basic | no catalyst no_water solvent any temperature

Products

Ketene-Nu-Alkoxide

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R3 = A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: acid | no catalyst no_water solvent room temperature

Products

Favorskii-Rearrangement-Br

References: 0,1

Condition to enforce:

R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent high temperature

Products

Hexadehydro-Diels-Alder-Reaction-Nu-Nitrile-and-El-Hydrogen

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent any temperature

Products

Hexadehydro-Diels-Alder-Reaction-Nu-Alkoxide-and-El-Hydrogen

References: 0

Condition to enforce:

R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = A-Aliphatic-Carbon, A-Aromatic-Carbon

Reactants

pH: basic | no catalyst water solvent any temperature

Products