Index
Oxa-Vinylcyclopropane-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
Reactants
Products
Ketene-Cycloaddition-3+2
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
Reactants
Products
Buchner-Ring-Expansion-C
References: 0
Special Conditions : SIDE REACTION
Reactants
Products
Ketene-Nu-Carboxyl-H
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R3 = H, A-Aromatic-Carbon, A-Aliphatic-Carbon, Vinyl-Group
Reactants
Products
Oxy-Cope-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
Reactants
Products
Ozonolysis-Alkene-Oxidative
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
R4 = H, A-Aliphatic-Carbon
Reactants
Products
Ozonolysis-Alkyne
Condition to enforce:
R1 = A-Aliphatic-Carbon, A-Aromatic-Carbon, H
R2 = A-Aliphatic-Carbon, A-Aromatic-Carbon, H
Reactants
Products
Claisen-Rearrangement
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
Reactants
Products
1,3-Dipolar-Cycloaddition-Type-I
References: 0
Reactants
Products
Hexadehydro-Diels-Alder-Reaction-Nu-Nitrite-and-El-Hydrogen
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Diels-Alder-4+2-Nitrogen
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = L-A
R3 = L-A
R4 = H, A-Aliphatic-Carbon
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A
Avoid formation of:
fragment = 4-membered-ring
Reactants
Products
Petasis-Ferrier-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R6 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R7 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R8 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
McCormack-Reaction
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R6 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R7 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R8 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R9 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Neber-Rearrangement
References: 0
Condition to enforce:
R1 = L-A
R2 = L-A, Vinyl-Group
R3 = L-A, Vinyl-Group
R4 = L-A
Reactants
Products
Ene-Reaction-C=C
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A
Avoid formation of:
fragment = 3-membered-ring, 4-membered-ring, 5-membered-ring, A-Cyclobutene, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5
Reactants
Products
Claisen-Rearrangement-Aromatic
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A
Reactants
Products
Hexadehydro-Diels-Alder-Reaction-Nu-Carbonyl-and-El-Hydrogen
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Hexadehydro-Diels-Alder-Reaction-Nu-Thiolate-and-El-Hydrogen
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Electrocyclic-Ring-Opening
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
R4 = H, A-Aliphatic-Carbon
R5 = H, A-Aliphatic-Carbon
R6 = H, A-Aliphatic-Carbon
Reactants
Products
Sommelet-Hauser-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon
Reactants
Products
Vinylcyclopropane-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
Reactants
Products
Ketene-Cycloaddition-4+2
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
Reactants
Products
Wharton-Reaction
References: 0
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon
Reactants
Products
Overman-Rearrangement-Pt1
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
Reactants
Products
Irreversable-Azo-Cope-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A
Reactants
Products
Nazarov-Cyclization
References: 0
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon
R5 = L-A, A-Aromatic-Carbon
Reactants
Products
Ketene-Nu-Hydroxyl
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
Reactants
Products
Diels-Alder-4+2
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = L-A
R3 = L-A
R4 = H, A-Aliphatic-Carbon
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A
R10 = L-A
Avoid formation of:
fragment = 4-membered-ring
Reactants
Products
Favorskii-Rearrangement-Cl
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
Reactants
Products
Buchner-Ring-Expansion-N
References: 0
Special Conditions : SIDE REACTION
Reactants
Products
Hexadehydro-Diels-Alder-Reaction-Nu-Hydroxyl-and-El-Hydrogen
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Ene-Reaction-C=O
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
Avoid formation of:
fragment = 3-membered-ring, 4-membered-ring, A-Cyclobutene, 5-membered-ring, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5
Reactants
Products
Nitrone-Olefin-3+2-Cycloaddition
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Ene-Reaction-C=N
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
Avoid formation of:
fragment = 3-membered-ring, 4-membered-ring, A-Cyclobutene, 5-membered-ring, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5
Reactants
Products
Aza-Vinylcyclopropane-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
Reactants
Products
Conia-Ene-Reaction
References: 0
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
Avoid formation of:
fragment = 3-membered-ring, 4-membered-ring, 5-membered-ring, A-Cyclobutene, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5
Reactants
Products
1,3-Dipolar-Cycloaddition-Type-II
References: 0
Reactants
Products
Hexadehydro-Diels-Alder-Reaction-Nu-Amino-and-El-Hydrogen
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
R6 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
Reactants
Products
Ene-Reaction-C=S
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
Avoid formation of:
fragment = 3-membered-ring, 4-membered-ring, 5-membered-ring, A-Cyclobutene, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5
Reactants
Products
Newman-Kwart-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Staudinger-Synthesis
References: 0
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon
Reactants
Products
Ozonolysis-Alkyne-Terminal
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Buchner-Ring-Expansion-O
References: 0
Special Conditions : SIDE REACTION
Reactants
Products
Aziridine-1-3-Dipole-Formation
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = A-Carbonyl, Nitronium
R3 = A-Carbonyl, Nitronium
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Tiffeneau-Demjanov-Rearrangement
References: 0
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon
Reactants
Products
Thio-Claisen-Rearrangement
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
Reactants
Products
Ketene-Nu-Amino
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
Reactants
Products
Azo-Vinylcyclopropane-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
Reactants
Products
Hexadehydro-Diels-Alder-Reaction-Nu-Phosphonate-and-El-Hydrogen
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R6 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Ene-Reaction-N=N
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
R4 = H, A-Aliphatic-Carbon
R5 = H, A-Aliphatic-Carbon
R6 = H, A-Aliphatic-Carbon
R7 = H, A-Aliphatic-Carbon
Avoid formation of:
fragment = 3-membered-ring, 4-membered-ring, 5-membered-ring, A-Cyclobutene, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5
Reactants
Products
Hexadehydro-Diels-Alder-Reaction-Nu-Carboxyl-and-El-Hydrogen
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Azo-Cope
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
Reactants
Products
Diels-Alder-4+2-Oxygen
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = L-A
R3 = L-A
R4 = H, A-Aliphatic-Carbon
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
Avoid formation of:
fragment = 4-membered-ring
Reactants
Products
Ketene-Cycloaddition-2+2
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
Reactants
Products
Enolate-Claisen-Rearrangement
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
Reactants
Products
Overman-Rearrangement-Pt2
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
Reactants
Products
Ketene-Nu-Alkoxide
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
R3 = A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Favorskii-Rearrangement-Br
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
Reactants
Products
Hexadehydro-Diels-Alder-Reaction-Nu-Nitrile-and-El-Hydrogen
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Hexadehydro-Diels-Alder-Reaction-Nu-Alkoxide-and-El-Hydrogen
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products