Index
Imine-Tautomerization-EWG-Phosphonate-EWG3-Nitrile
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Aston-Greenburg-Rearrangement-X-Bromine
References: 0
Condition to enforce:
R6 = A-Aliphatic-Carbon
Reactants
Products
Fritsch-Buttenberg-Wiechell-Rearrangement-Cl
References: 0
Condition to enforce:
R1 = A-Aromatic-Carbon
R2 = A-Aromatic-Carbon
Reactants
Products
Chan-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Imine-Tautomerization-EWG-Carbonyl-EWG3-Nitrile
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aromatic-Carbon, A-Aliphatic-Carbon, Vinyl-Group
Reactants
Products
Fries-Rearrangement-ortho
References: 0
Special Conditions : SIDE REACTION
Avoid formation of:
fragment = 3-membered-ring, 4-membered-ring, A-Cyclobutene, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5
Reactants
Products
Benzilic-Acid-Rearrangement
References: 0
Condition to enforce:
R1 = A-Aromatic-Carbon
R2 = A-Aromatic-Carbon
Reactants
Products
Lossen-Rearrangement
References: 0
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
Reactants
Products
Aston-Greenburg-Rearrangement-X-Chlorine
References: 0
Condition to enforce:
R6 = A-Aliphatic-Carbon
Reactants
Products
Bamberger-Rearrangement
References: 0
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon
Reactants
Products
Hofmann-Rearrangement-Cl
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Eschenmoser-Claisen-Rearrangement
References: 0
Condition to enforce:
R1 = L-A
R2 = L-A
R3 = L-A
R4 = L-A
R5 = L-A
R6 = L-A
R7 = L-A
R8 = L-A
R9 = L-A
Reactants
Products
Mumm-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
Reactants
Products
Semi-Pinacol-Rearrangement-Alkene
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
R4 = H, A-Aliphatic-Carbon
R5 = H, A-Aliphatic-Carbon
Reactants
Products
Meisenheimer-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
Reactants
Products
Rupe-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Hayashi rearrangement
References: 0
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon
R5 = A-Aromatic-Carbon
Reactants
Products
Aston-Greenburg-Rearrangement-X-Sulfonate
References: 0
Condition to enforce:
R6 = A-Aliphatic-Carbon
Reactants
Products
Curtius-Rearrangement
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
Reactants
Products
Criegee-Rearrangement
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Fritsch-Buttenberg-Wiechell-Rearrangement-Br
References: 0
Condition to enforce:
R1 = A-Aromatic-Carbon
R2 = A-Aromatic-Carbon
Reactants
Products
Hofmann-Rearrangement-Br
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Pinacol-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = L-A, A-Aromatic-Carbon
R2 = L-A, A-Aromatic-Carbon
R3 = L-A, A-Aromatic-Carbon
R4 = L-A, A-Aromatic-Carbon
Reactants
Products
Meyer-Schuster-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Lobry-de-Bruyn-Van-Ekenstein-Transformation
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Fries-Rearrangement-para
References: 0
Special Conditions : SIDE REACTION
Avoid formation of:
fragment = 3-membered-ring, 4-membered-ring, A-Cyclobutene, A-Cyclobutene-Aromatic, A-Cyclobutadiene, A-Cyclo-Double-Aromatic-pentene, A-Cyclopentene-Aromatic, bridged_meta_tether_2, A-Cyclo-Double-Aromatic-Pentene3, bridged_para_tether_2, bridged_para_tether_3, bridged_para_tether_4, bridged_para_tether_5, bridged_meta_tether_1, bridged_meta_tether_2, bridged_meta_tether_3, bridged_meta_tether_4, bridged_meta_tether_5
Reactants
Products
Cornforth-Rearrangement
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
Reactants
Products
Imine-Tautomerization-EWG-Nitrite-EWG3-Nitrile
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Semi-Pinacol-Rearrangement-Nu-Sulfonate
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Imine-Tautomerization-EWG-Carboxyl-EWG3-Nitrile
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group
Reactants
Products
Amadori-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Semi-Pinacol-Rearrangement-Nu-Chlorine
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Pummerer-Rearrangement
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Meisenheimer-Rearrangement-Conjugated
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
R4 = H, A-Aliphatic-Carbon
R5 = H, A-Aliphatic-Carbon
R6 = H, A-Aliphatic-Carbon
R7 = H, A-Aliphatic-Carbon
Reactants
Products
Baker-Venkataraman-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R5 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R6 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Avoid formation of:
fragment = 4-membered-ring, A-Cyclobutene-Aromatic
Reactants
Products
Piancatelli-Rearrangement
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Aston-Greenburg-Rearrangement-X-Iodine
References: 0
Condition to enforce:
R6 = A-Aliphatic-Carbon
Reactants
Products
Semi-Pinacol-Rearrangement-Nu-Iodine
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
McFadyen-Stevens-Reaction
References: 0
Condition to enforce:
R1 = L-A
R2 = L-A
Reactants
Products
Wolff-rearrangement
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
Reactants
Products
Imine-Tautomerization-EWG-Nitrile-EWG3-Nitrile
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon, Vinyl-Group-No-Oxygen, A-Alkoxide, Hydroxyl, A-Aliphatic-Nitrogen
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Kornblum-DeLaMare-Rearrangement
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
R4 = H, A-Aliphatic-Carbon
R5 = H, A-Aliphatic-Carbon
Reactants
Products
Beckmann-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon
R2 = H, A-Aliphatic-Carbon
R3 = H, A-Aliphatic-Carbon
R4 = H, A-Aliphatic-Carbon
Reactants
Products
Semi-Pinacol-Rearrangement-Nu-Bromine
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R4 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Chapman-Rearrangement
References: 0
Special Conditions : SIDE REACTION
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R2 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
R3 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products
Thiocarbamate-Resonance
References: 0
Condition to enforce:
R1 = H, A-Aliphatic-Carbon, A-Aromatic-Carbon
Reactants
Products